Basic Silica is silicon dioxide or SiO2, it occurs in a crystalline
state, an amorphous (shapeless) state and in impure forms such as quartz,
opal and sand. It is the primary constituent of the Earth's crust. It is usually
found in the form of silicates. Silicones are synthetic polymers and are made
by combining oxygen and silicon in high temperatures and pressures. In cosmetics
the crystalline form of silica is being avoided for health and safety reasons
and only the amorphous forms and silicates are being used.
Silicones are a large group of synthetic compounds that can
include large and small polymers. Depending on the formula and the degree
of polymerization and cross-linking of the polymers, they may be slippery
liquids, waxes, or rubbers. Silicone compounds are used in cosmetics to form
films and absorb sebum from the skin and to prevent shine. They have a low
coefficient of friction and add slip in most product applications. There are
also medical grade elastomers that are being used.
Silicones are used as emollients and skin softeners, as lubricants,
thickeners, and volatile liquids that make products feel smooth, but evaporate
without leaving a greasy residue. Cyclopentasiloxane is a low viscosity, volatile
liquid used as a carrier. It lubricates, and prevents hair sprays from being
sticky to the touch. It evaporates completely, leaving no residue. Dimethicone
is another name for polydimethylsiloxane and is used to impart a soft velvety
feel to hair or skin products. It is also used as an emulsifier for "water-in-oil"
emulsions. It comes in many viscosity grades and can be used to make skin
protectant claims. Trimethylsiloxysilicate is a film forming resin, used to
keep hand lotions and sunscreens from washing off. Cetearyl methicone is a
polysiloxane wax. It replaces petrolatum in products such as hand lotions
to give them a non-greasy feel. Silicone products all have good solubility
and compatibility with one another.
The following tip comes from dermatologist Dr. Zoe Diana
Draelos, MD, Clinical Associate Professor of Dermatology at Wake Forest University
School of Medicine in Winston-Salem, NC. She can help you find the best cosmetics
for sensitive skin. She also has her dermatology office in High Point, NC.
She is a member of the SCC and frequent lecturer at many SCC meetings nationwide.
She recommends using foundations based on silicones. While powder is preferred
to protect sensitive skin and to absorb excess oils and reduce skin shine,
women choosing a liquid foundation should look for the ones with a silicone
base. Liquid facial foundations based on silicone do not cause acne, and silicone
has a very low incidence of skin irritation. This comes from a prominent dermatologist.
So to all those websites that sound like they know every skull and crossbones
ingredient out there try again.
According to Dow Corning, a major supplier of silicones to
the cosmetics and pharmaceutical industries, silicones have become a major
presence in color cosmetics because they offer a soft, silky and non-oily
feel during and after application. Their multifunctional properties offer
flexibility for developing new textures and stable systems. They are more
than simple additives, they offer important benefits in formula functionality
and processing. They also go on to say that Dow Corning silicones boost performance
and improve the feel of sunscreens. In decorative cosmetics, silicone waxes
that are used in lipsticks and foundation ensure that the colored pigments
used are reliably held in place and do not migrate. The FDA recognizes silicones
(dimethicone) as ingredients that can be used to make OTC drug claims as a
"skin protectant." So even the US Government recognizes the safety
of silicones in cosmetics and personal care products.
Mind you if there is an ingredient that is deemed potentially
hazardous, the industry wastes no time in removing this suspect ingredient
from all its formulations. Such is the case with D4 cyclomethicones or cyclotetrasiloxane
(Dow Corning 244 Fluid for example). The industry does not use this ingredient
any longer and has moved to blends of the D5 and D6 grades of cyclomethicones.
But you will still have those out there that still think the industry uses
the D4 grade and base all their negative publicity on this outdated information,
which is not fair to the consumer or the industry.